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Thermophysical Data for Process Design
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DDB# Name CAS-RN Formula
90 Hydrogen fluoride 7664-39-3 HF Overview Details
174 Water 7732-18-5 H2O Overview Details
24281 Zirconium(IV) hydroxide 14475-63-9 H4O4Zr Overview Details
1004615 Tetrazirconium hexahydroxy decafluoride
trihydrate		 Zr4(OH)6F10*3H2O Overview Details
1004616 Zirconium tetrafluorid trihydrate ZrF4*3H2O Overview Details
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate HZrF5*4H2O Overview Details
1004618 Dihydrogen hexafluorozirconate(IV) dihydrate H2ZrF6*2H2O Overview Details
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Mixture Data

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Vapor-Liquid Equilibria (VLE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 23 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Gas Solubilities (GLE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 6 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Heat Capacities of Mixtures, Excess Heat Capacities (CPE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 3 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

(A)zeotropic Data (AZD)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 24 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Solid-Liquid Equilibria (SLE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 6 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Vapor-Liquid Equilibria of Electrolyte Systems (ELE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 5 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Densities and Volumes of Mixtures, Excess Volumes (VE)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 4 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Further Thermodynamic Properties (X)
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 6 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Total
DDB# Name 174 24281 1004615 1004616 1004617 1004618 Dihydrogen hexafluorozirconate(IV) dihydrate
90 Hydrogen fluoride 77 n.a. n.a. n.a. n.a. n.a.
174 Water n.a. n.a. n.a. n.a. n.a.
24281 Zirconium(IV) hydroxide n.a. n.a. n.a. n.a.
1004615 Tetrazirconium hexahydroxy decafluoride trihydrate n.a. n.a. n.a.
1004616 Zirconium tetrafluorid trihydrate n.a. n.a.
1004617 Hydrogen pentafluorozirconate(IV) tetrahydrate n.a.

Dortmund Data Bank Version: February 2024
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